VFBATTERY REPORT

Sodium Ion

Pages 390–396 (7 pages)

Battery Report 2024, page 391: Sodium Ion
Text on page 391

Sodium-Ion Batteries - An Emerging Alternative To Lithium-Ion COST PROJECTIONS OF NAION BATTERIES

TEARDOWN OF FOUR COMMERCIAL NAION CELLS

Research by Yao et al. 1 indicates that Na-ion batteries could achieve cost parity with low-cost Li-ion variants by the early 2030s. The study explored over 6,000 scenarios to assess various development roadmaps and market conditions, highlighting that substantial R&D progress is crucial for enabling this transition.

Dorau et.al 2 provide a comprehensive analysis of four commercially available cylindrical sodium-ion batteries, revealing key insights into their structural and electrochemical performance.

The research highlights a significant manufacturing pipeline for Na-ion cells, with over 240 GWh announced through 2030, indicating strong industry interest and investment in this technology as a response to lithium price volatility.

The batteries, with capacities ranging from 1.3 Ah to 10 Ah and voltages between 3.0 V and 3.1 V, utilized nickel-manganese-iron layered oxides as cathodes and hard carbon anodes with particle sizes of 212 μm. Separator materials included polyethylene with protective α-Al2O3 coatings. Doping the cathodes with zirconium or copper improved ion diffusion and structural stability, mitigating degradation. Specific area capacities ranged from 1.29 to 1.98 mAh/cm2. At 0°C, all cells showed sodium plating risks, potentially compromising safety during high-rate charging.

Na-ion batteries are no longer confined solely to the academic domain and have started making their way into the commercial world.

Source: 1 Yao, A., Benson, S.M. & Chueh, W.C. Critically assessing sodium-ion technology roadmaps and scenarios for techno-economic competitiveness against lithium-ion batteries. Nat Energy 2025; 2 Comprehensive Analysis of Commercial Sodium-Ion Batteries: Structural and Electrochemical Insights, Filip Adam Dorau et al 2024 J. Electrochem. Soc. 171 09052

Extracted from the PDF; charts and images may read imperfectly.

Page 391 · 2/7