New / Alternative Chemistries
Pages 618–629 (12 pages)
Text on page 629
Halogen-driven Ion Transport Homogenization in 3D Hierarchical MOF for Ultrastable Solid-state LMB The hierarchical pore channels of MIL100 confine LiI to form a conductive ionic network, while its triple-level cross-linked multi-stage porous restricts TFSI− anion mobility, enabling rapid Li+ transport and uniform deposition by optimizing ion flux and suppressing space charge effects.
The LFP/ELiI/Li cell delivers 120 mAh g−1 and maintains stable cycling for 600 cycles at 2C without noticeable capacity decay, and also sustains strong performance at high temperatures 60100 °C. When paired with NCM811, the ELiI electrolyte enables a pouch cell to exhibit excellent capacity and stable cycling at 1C, successfully powering an LED panel.
MECHANISM
PERFORMANCE
Halogen-engineered 3D MOF electrolytes deliver uniform lithium transport and plating, enabling ultrastable, fast-charging solid-state LMB. Source: Zhang X., et al. Angew. Chem. Int. Ed. 2025, 6437, e202511822.
Extracted from the PDF; charts and images may read imperfectly.
Page 629 · 12/12